|
Hi René. Even though you're just a fox, I'm sure you or one
of your friends can answer some of my questions. You see, I'm doing
a project for chemistry on, yeah, you guessed it, pulp and paper.
I'd just like to have some information on what kind of chemicals
you use in the process of pulping and making paper, and what products
come from those reactions. Chemical formulas and equations would
be very helpful. Thank you for all your help.
I have compiled a list of journals that you can reference
for additional information:
PULP AND PAPER MANUFACTURE
Second Edition, Vol 1
"The Pulping of Wood"
Editors: Ronald G. MacDonald ( no, not the guy with the big red
feet!)
John N. Franklin
McGraw Hill Book Company
CHEMICAL RECOVERY IN THE ALKALINE PULPING
PROCESSES
A Project of the Alkaline Pulping Committee of the Pulp Manufacture
Division
Edited by Gerald Hough
Tappi Press, Atlanta Georgia
PULP BLEACHING: Principles and Practice
Carlton W. Dence
College of Environmental Science & Forestry, Retired
State University of New York
Syracuse, NY, USA
and
Douglas W. Reeve
Department of Chemical Engineering & Applied Chemistry
Pulp & Paper Centre
University of Toronto
Toronto, Ontario
Tappi Press
Atlanta, Georgia (1996)
Don McCabe - Sr. Process Engineer, Irving Pulp & Paper
Is it possible / reasonable to try to grow evergreens and/or
hardwoods from seed on my woodlot in Nova Scotia? Can I get seedlings
from Irving in any event?
Concerning your question of growing softwoods or hardwoods
from seed. Yes, most certainly it is possible to grow trees from
seed, but I would caution you that the results may not be as
favourable as you would like.
Unless you have a greenhouse or similar climate controlled
area, you would probably not do as well as mother nature would
in starting out those trees. I would not want to discourage you
from experimenting as this can be a great learning experience
and most rewarding, but on a semi-commercial scale such as for
your woodlot, this method would be impractical. A better success
rate can be achieved affordably by purchasing seedlings from
the Department of Natural Resources. Four years ago in NB, 1000
red pine seedings could be purchased for approximately $120.
These seedlings are usually 15-20 cm tall and have already gone
through the critical survival period, so your success rate (depending
on site suitability, etc) would be over 75 -80%.
I would encourage you to try some seeds though, and will provide
you with the name and address for a free publication that is
invaluable in this regard. "Trees and shrubs from seed:
Gathering, storing and planting" by The Tree Project 180
St. John Street, Fredericton, NB E3B 4A9.
Also provided is a listing of Nurseries in NS (and one in
NB) that you may be able to buy seeds from, or at the very least,
buy seedlings.
OCTA EVERGREEN
Paul Bourque
RR # 7 Amhurst NS
B4H 3Y5
Tel 902-667-3525
Fax 902-667-0677
STRATHLORNE FOREST NURSERY
P.O. Box 489
Inverness, NS
BOE 1N0
Tel 902-258-2626
fax 902-258-2330
NOVA SCOTIA TREE BREEDING CENTRE
P.O. Box 190
Debert, NS
BOM 1GO
tel 902-662-3300
fax 902-662-3066
NOVA TREE SEEDS
Box 102, Middle Musquodoboit
Nova Scotia BON 1XO
tel 902-384-2979
OLD RIDGE NURSERY
Bruce Fraser
RR#4, St, Stephen, NB
E3L 2Y2
tel 506-465-2770
fax 506-466-0881
Kelly Honeyman - Naturalist, J. D. Irving, Limited (Woodlands)
Hart Kuntz - Nursery Manager, Sussex Tree Nursery
I recently visited your web-site in hopes of finding a
definition of "black liquor". What I am trying to determine
is how this product is involved in the paper making process.
I am an engineer but have limited knowledge of the papermaking
industry...so please, a not too technical answer would be greatly
appreciated.
To understand "black liquor" requires some understanding
of what wood is and how pulp is produced.
Simply stated, wood is composed of wood fibres (cellulose)
and an organic glue called lignin. The chemical pulping process
is used to separate the cellulose from the lignin.
To pulp wood, a large pot called a digester is filled with
wood chips and a fresh charge of liquor (called white liquor
containing active chemicals) is added and cooked for a preset
period of time. During the cooking process, these chemicals dissolve
the lignin and leave the cellulose for the production of pulp.
These "cooked" chemicals and dissolved lignin are referred
to as "black liquor". The black liquor is then concentrated,
burned and the spent chemicals are regenerated (recovered) back
to active chemicals that can be used again. You are right in
saying that black liquor is a by-product of the pulping industry,
but this product is never disposed of, but rather is recycled.
Don McCabe - Senior Process Engineer, Irving Pulp &
Paper
I am writing a report on how paper disintigrates in different
types
of earth substances. I am having a hard time finding data to
back
up my thoughts.
There are several factors which affect the way paper disintegrates
or decomposes. These include but are not limited to: moisture,
nitrogen availability, pH, paper type and surface area exposed.
Paper will eventually decompose in almost any soil type but the
process can be greatly accelerated when these factors are controlled,
such as in a composting system.
All of these factors influence the ability of microbes (bacteria
& fungi) to
decompose the paper. Moisture is essential to the process as
most of the microbes are found in thin liquid films on the surface
of materials. Since paper is dry, moisture would have to be present
in the soil or added in order for decomposition to occur.
Nitrogen availability will differ with different soil types.
Paper contains a large amount of carbon but has few other nutrients.
Carbon is the main energy source (food) for microbes but nitrogen
is needed for microbial population growth as it is necessary
for protein production. If nitrogen is limited, the microbe populations
will remain small and it will take longer for them to decompose
(consume) the available carbon.
The best pH range for the decomposition process is 5.5 - 8.
The lower or more acidic end of this range favours the growth
of fungi which break down lignin and cellulose, the main components
of wood and therefore paper. This means that slightly acidic
soils will speed up the disintegration of paper. Soils which
are very acidic (pH < 5.5) or alkaline (pH>8) will slow
decomposition because these conditions limit microbial activity.
Different types of paper will decompose at different rates.
For instance,
some paper making processes remove lignin, a component of wood
which gives the cells structure and strength. Lignin is a very
difficult compound to decompose. If the paper contains little
lignin it will be more easily broken down. Paper may also differ
in the amount of filler, or clay it contains. Generally, paper
which is smooth and glossy (e.g. magazine paper) contains more
clay than paper which is dull or rough (e.g. newspaper). Clay
is inorganic and cannot be decomposed. The clay can actually
physically cover the organic particles in the paper, slowing
down the decomposition.
This brings us to the last factor, surface area exposed. The
microbes have to be physically on the organic material in order
for decomposition to occur. If the surface area is increased
(e.g. by shredding the paper) then there would be more places
for the microbes to grow.
Other factors which would affect decomposition include oxygen
supply,
temperature and other nutrients available. These factors would
be a
concern in a composting system but would probably not be of concern
when looking at disintegration of paper in soils.
Paula Noel - Composting Project, Irving Paper
[ Back ] [ Next
] |